Product ID:94012, SHELLZONE ANTIFREEZE
MSDS Date:06/28/1989
FSC:6850
NIIN:00N033509
MSDS Number: BNVSR

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Preparer: G.A. VAN GELDER

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB SUCH

RTECS: 9999999ZZ

FLUSH AREA W/H*2O TO REMOVE TRACE RESIDUE. SM

RTECS: 9999999ZZ

OF SURF WATERS, SEWERS & WATERWAYS ENTERING/LEADING

RTECS: 9999999ZZ

PUBLIC OR ENVIRONMENT OCCURS OR IS LIKELY TO OCCUR.

RTECS: 9999999ZZ

(ORAL,RAT)4 G/KG.

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 84-94%

OSHA PEL 50 PPM, C

ACGIH TLV: 50 PPM, C

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

(ORAL,RAT)14.8 G/KG.

CAS: 111-46-6

RTECS: ID5950000

Fraction By Weight: 0-10%

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 2-4%

SALTS; (INORGANIC/ORGANIC SALTS)

Fraction By Weight: 2-4%

1 WAS ADMIN BY GAVAGE @ DAILY DOSES OF 1.25 G/KG &

RTECS: 9999999ZZ

MICE, THERE WAS INCR IN NUMBER OF MALFORMED FETUSES @

RTECS: 9999999ZZ

THERE WAS ALSO EVID OF MATERNAL TOXICITY AT ALL DOSE

RTECS: 9999999ZZ

2 GLASSES OF H*2O & INDUCE VOMIT BY TOUCHING

RTECS: 9999999ZZ

IF VICTIM

RTECS: 9999999ZZ

(1 TBSP) SYRUP OF IPECAC. IF SYMPS SUCH AS LOSS OF

RTECS: 9999999ZZ

LAVAGE SHOULD BE CONSIDERED FOLLOWING INTUBATION

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS 1 & 2.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:ING 1:MOD TO SEV IRRIT. VAPS CAN
ALSO CAUSE SEV IRRIT. SKIN:INGS 1 & 2:MILDLY IRRIT & SLIGHTLY TOX
ON PRLNG/RPTD CONT. INHAL:VAPS ARE MILDLY TO MARKEDLY IRRIT TO
LUNGS DEPENDING ON EXPOS LEVELS. I NGEST:PROD MAY BE HARMFUL/FATAL
IF SWALLOWED; MAY PRDCE CNS DEPRESS & KIDNEY DMG WHICH MAY BE
FATAL. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INGEST OF ING 2 MAY ALSO PRDCE LIVER
DMG. SIGNS & SYMPS:IRRIT AS NOTED. EARLY TO MOD CNS DEPRESS MAY BE
EVID BY GIDD, HDCH, DIZZ & NAUS; IN EXTREME CASES, UNCON & DEATH
MAY OCCUR. KIDNEY DMG MAY BE EVID BY CHANGES IN URINE OUTPUT,URINE
APPEAR/EDEMA (SWELL FROM FLUID RETENTION). LIVER DMG MAY BE EVID
(SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN, EYE & RESP
DISORDERS MAY BE AGGRAVATED BY EXPOS TO PROD. IMPAIRED KIDNEY &
LIVER FUNCTIONS FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY
EXPOS TO PROD.

First Aid:EYE:IMMED FLUSH W/PLENTY OF H*2O FOR @ LST 15 MINS WHILE
HOLDING EYELIDS OPEN. GET MD. SKIN:FLUSH W/H*2O. IF IRRIT OCCURS,
GET MD. INHAL:REMOVE VICTIM TO FRESH AIR & PROVIDE O*2 IF BRTHG IS
DFCLT. GET MD. INGEST:DO NOT GIVE LIQS IF VICTIM IS UNCON/VERY
DROWSY. OTHERWISE, GIVE NO MORE THAN 2 GLASSES OF H*2O & INDUCE
VOMIT BY GIVING 30CC (2 TBSPS) SYRUP OF IPECAC. IF IPECAC IS
UNAVAIL, GIVE (ING 8)

Flash Point Method:SCC
Flash Point:246F,119C
Extinguishing Media:USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR
CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . MATERIAL WILL NOT BURN UNLESS PREHEATED.
COOL FIRE EXPOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE
CAUT JUDGMENT WHEN CLEANING UP LG SPILLS. LG SPILLS:WEAR NIOSH/MSHA
APPRVD RESP & PROT CLTHG AS APPROP. SHUT OFF SOURCE OF LEAK IF SAFE
TO DO SO. DIKE & CO NTAIN. REMOVE W/VACUUM TRUCK/PUMP TO STOR/(ING
12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT W/EYES. AVOID
PROLONGED/REPEATED CONTACT W/SKIN. STORE IN A COOL, DRY PLACE
W/ADEQUATE VENTILATION.
Other Precautions:KEEP AWAY FROM FLAMES & HIGH TEMPERATURES.

Respiratory Protection:IF EXPOS MAY/DOES EXCEED OCCUP EXPOS LIMITS USE
A NIOSH/MSHA APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. I/A/W 29
CFR 1910.134 USE EITHER NIOSH/MSHA APPROVED ATMOSPHERE-SUPPLYING
RESPIRATOR OR AIR-PU RIFYING RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:USE VENTILATION AS REQUIRED TO CONTROL VAPOR
CONCENTRATIONS.
Protective Gloves:NITRILE, NEOPRENE, PVC/NATRL RUB GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:CHEM RESISTANT CLTHG AS REQD TO MIN CONT.
EYE WASH FOUNTAINS & SAFETY SHOWERS SHOULD BE AVAIL FOR EMERGENCY
USE.
Work Hygienic Practices:WASH W/SOAP & H*2O BEFORE EATING, DRINKING,
SMOKING/USING TOILET FACILITIES. LAUNDER CONTAM CLTHG BEFORE REUSE.
Supplemental Safety and Health
EFTS OF OVEREXP:BY LOSS OF APPETITE, JAUNDICE (YELLOWISH SKIN COLOR) &
SOMETIMES PAIN IN UPPER ABDOMEN ON RIGHT SIDE. INTENT ABUSE,
MISUSE/OTHER MASSIVE EXPOS MAY CAUSE MULTIPLE ORGAN DMG &/OR DEATH.
RARE CASES OF ING 1 SENSIT (ALLERGY) HAVE BEEN PUBLISHED BUT
ALLERGY TO ING 1 IS NOT COMMON PHENOMENON. WHEN ING (ING 5)

Boiling Pt:B.P. Text:>330F,>166C
Vapor Density:>1
Spec Gravity:1.373 (H*2O=1)
Evaporation Rate & Reference:<0.01 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:BLUE GREEN, SLIGHTLY VISCOUS LIQUID; MILD ODOR.

Stability Indicator/Materials to Avoid:YES
KEEP AWAY FROM STRONG OXIDIZING MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO & UNIDENTIFIED ORGANIC COMPOUNDS
MAY BE FORMED DURING COMBUSTION.

Waste Disposal Methods:PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE W/LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.